Beilstein J. Org. Chem.2013,9, 2803–2811, doi:10.3762/bjoc.9.315
diglycidyl ether to give novel oligomeric thermoresponsive epoxide–amineadducts. These oligomers exhibit a lower critical solution temperature (LCST) behavior in water. The solubility properties were influenced with randomly methylated β-cyclodextrin (RAMEB-CD) and the curing properties of the amine–epoxide
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Graphical Abstract
Scheme 1:
Synthesis of the monomers 5 and 7, as well as the chemical structure of the diepoxide 8, comprising...
Beilstein J. Org. Chem.2010,6, 938–944, doi:10.3762/bjoc.6.105
were used as the initiator for the ring-opening polymerization of ε-caprolactone to produce a graft copolymer.
Keywords: addition oligomerization; epoxide-amineadducts; microwave; ring-opening polymerization; transfer hydrogenation; Introduction
In the last decade the use of microwave (MW
former work on the formation of hyperbranched epoxide-amineadducts via microwave-assisted heterogeneous catalytic transfer hydrogenation [22], we report herein the synthesis of an linear oligo(amino alcohol). The hydroxy groups of the latter were then used as an initiator for the ring-opening
polymerization (ROP) of ε-caprolactone to construct a new class of graft copolymers.
Results and Discussion
Formation of epoxide-amineadductsEpoxide-amineadducts based on diglycidyl ether of bisphenol A (1) and 4-aminoanisole (3) were synthesized in a MW-assisted one-pot reaction. Thus, 4-nitroanisole (2) was
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Graphical Abstract
Scheme 1:
One-pot synthesis of epoxide-amine adducts via MW-assisted transfer hydrogenation.